Lightweight ceramic components containing a large volume of designed porosity possess a rather exceptional array of properties, besides displaying the typical favorable characteristics of ceramics, such as wear resistance, refractoriness and chemical inertness. In fact, they have low density, thermal conductivity, dielectric constant, thermal mass and, simultaneously, high specific strength, permeability, thermal shock resistance, and specific surface area. Namely, foam ceramics have fine pore size, excellent stability and high integrity, being as light as < 323 kg/m3 and with use temperatures as high as > 1700οC. Their unique combination of properties allows them to significantly extend the range of materials properties, and makes them suitable for a wide range of advanced applications. These include filtration, radiant burners, catalyst supports, biomedical devices, kiln furniture, reinforcement for metal matrix composites, bioreactors, thermal protection systems, components in solid oxide fuel cells, lightweight structures, heat exchangers, ablative structures, etc. Moreover, most of the oxide and non-oxide ceramics and ceramic matrix composites have excellent mechanical properties including hardness and mechanical strength, but they do not present enough dynamic strength. To increase density and dynamic strength a common technique that is used is spark plasma sintering, aiming to high tech applications, including automotive and aerospace applications, ballistic armor, electronics, thermal insulators and engine components. In particular, the densities of SiBCN (2.56 g/cm3) and SiC (3.29 g/cm3) are considerably less than that of Al2O3 (3.98 g/cm3), targeting mainly to defence and aerospace applications. .